[Minor PR] Quotes in documentation changed into code blocks (GH-99536)

Minor formatting fix in documentation

(cherry picked from commit efccd04)

Co-authored-by: Bart Broere <mail@bartbroere.eu>
Co-authored-by: Shantanu <12621235+hauntsaninja@users.noreply.github.com>

Doc/library/subprocess.rst

@@ -1567,13 +1567,17 @@ If you ever encounter a presumed highly unusual situation where you need to
 prevent ``vfork()`` from being used by Python, you can set the
 :attr:`subprocess._USE_VFORK` attribute to a false value.
 
+::
+
    subprocess._USE_VFORK = False  # See CPython issue gh-NNNNNN.
 
 Setting this has no impact on use of ``posix_spawn()`` which could use
 ``vfork()`` internally within its libc implementation.  There is a similar
 :attr:`subprocess._USE_POSIX_SPAWN` attribute if you need to prevent use of
 that.
 
+::
+
    subprocess._USE_POSIX_SPAWN = False  # See CPython issue gh-NNNNNN.
 
 It is safe to set these to false on any Python version. They will have no