diff --git a/include/cantera/kinetics/TwoTempPlasmaRate.h b/include/cantera/kinetics/TwoTempPlasmaRate.h index 25f96d9328..00ac562346 100644 --- a/include/cantera/kinetics/TwoTempPlasmaRate.h +++ b/include/cantera/kinetics/TwoTempPlasmaRate.h @@ -48,9 +48,11 @@ struct TwoTempPlasmaData : public ReactionData * activation energy for electron is included. * * \f[ - * k_f = A T_e^b \exp (-E_a/RT) \exp (-E_{a,e}/RT_e) + * k_f = A T_e^b \exp (-E_{a,g}/RT) \exp (E_{a,e} (T_e - T)/(R T T_e)) * \f] * + * where \f$ T_e \f$ is the electron temperature, \f$ E_{a,g} \f$ is the activation + * energy for gas, and \f$ E_{a,e} \f$ is the activation energy for electron. * Ref.: Kossyi, I. A., Kostinsky, A. Y., Matveyev, A. A., & Silakov, V. P. (1992). * Kinetic scheme of the non-equilibrium discharge in nitrogen-oxygen mixtures. * Plasma Sources Science and Technology, 1(3), 207. diff --git a/interfaces/cython/cantera/reaction.pyx b/interfaces/cython/cantera/reaction.pyx index 11507b7f3c..d2977cbb78 100644 --- a/interfaces/cython/cantera/reaction.pyx +++ b/interfaces/cython/cantera/reaction.pyx @@ -283,11 +283,15 @@ cdef class TwoTempPlasmaRate(ArrheniusRateBase): .. math:: - k_f = A T_e^b \exp(-\tfrac{E_{a,g}}{RT}) \exp(-\tfrac{E_{a,e}}{RT_e}) - - where :math:`A` is the `pre_exponential_factor`, :math:`b` is the - `temperature_exponent`, :math:`E_{a,g}` is the `activation_energy`, and - :math:`E_{a,e}` is the `activation_electron_energy`. + k_f = A T_e^b \exp(-\tfrac{E_{a,g}}{RT}) \exp(\tfrac{E_{a,e}(T_e - T)}{R T T_e}) + + where :math:`A` is the + `pre_exponential_factor `, + :math:`b` is the `temperature_exponent `, + :math:`E_{a,g}` (``Ea_gas``) is the + `activation_energy `, and + :math:`E_{a,e}` (``Ea_electron``) is the + `activation_electron_energy `. """ _reaction_rate_type = "two-temperature-plasma"