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\documentclass[11pt]{article}
\title{Radiative Processes in Astrophysics}
\author{E. Chiang and A. Parsons}
\date{Fall, 2004}
\usepackage{graphicx}
\def\.{\dot}
\def\^{\hat}
\def\_{\bar}
\def\~{\tilde}
\def\hf{{1 \over 2}}
\def\imply{\Rightarrow}
\def\inv#1{{1 \over #1}}
\def\ddt{{d \over dt}}
\parindent=0mm
\parskip=3pt
\def\sqr#1#2{{\vcenter{\vbox{\hrule height.#2pt
\hbox{\vrule width.#2pt height#1pt \kern#1pt
\vrule width.#2pt}
\hrule height.#2pt}}}}
\def\square{\mathchoice\sqr34\sqr34\sqr{2.1}3\sqr{1.5}3}
\def\mean#1{\left\langle #1\right\rangle}
\def\sigot{\sigma_{12}}
\def\sigto{\sigma_{21}}
\def\eval#1{\big|_{#1}}
\def\tr{\nabla}
\def\dce{\vec\tr\times\vec E}
\def\dcb{\vec\tr\times\vec B}
\def\wz{\omega_0}
\def\ef{\vec E}
\def\ato{{A_{21}}}
\def\bto{{B_{21}}}
\def\bot{{B_{12}}}
\def\bfield{{\vec B}}
\def\ap{{a^\prime}}
\def\xp{{x^{\prime}}}
\def\yp{{y^{\prime}}}
\def\zp{{z^{\prime}}}
\def\tp{{t^{\prime}}}
\def\upx{{u_x^\prime}}
\def\upy{{u_y^\prime}}
\def\e#1{\cdot10^{#1}}
\usepackage{fullpage}
\usepackage{amsmath}
\usepackage{eufrak}
\begin{document}
\maketitle
\section*{Lecture 1}
\subsection*{Units}
Here are some terms pertaining to telescope observations:\par
aperture area ($\Delta A$), solid angle on sky ($\Delta \Omega
[\square ",\square^\circ , sr]$), exposure time ($\Delta t$), collects
energy ($\Delta E$), over waveband ($\Delta \nu [Hz^{-1}]$), but
$\Delta\lambda\ne {c\over \Delta\nu}$.
$${\Delta E\over\Delta t\Delta\nu\Delta A\Delta\Omega} \iff
{dE \over dt d\nu dA d\Omega} \equiv I_\nu$$
$I_\nu$ is the specific intensity per unit frequency.
Flux density is power per unit frequency passing through a
differential area whose normal is $\^n$. Thus, flux density is:
$$\boxed{F_\nu\equiv\int I_\nu\cos\theta d\Omega}$$
\subsection*{ Proof that Specific Intensity is conserved along a ray }
The power received by the telescope is:
$$P_{rec}=I_\nu d\Omega dA$$
where
$I_\nu(\alpha,\delta )$ is the intensity as a function of right-ascension
($\alpha$) and declination ($\delta$). Say that $\Sigma_\nu(\alpha,\delta)$
is the surface luminosity of a patch of sky (that is, the emitted intensity).
Then power emitted by patch of sky is:
$$P_{emit}=\Sigma_\nu{dA\over r^2}d\tilde A$$
Recognizing that $d\tilde A=d\Omega r^2$:
$$\Sigma_\nu=I_\nu$$
This derivation assumes that we are in a {\it vacuum} and that the
{\it frequencies of photons are constant}.
If frequencies change, then though specific intensity $I_\nu$ is not conserved,
${I_\nu\over\nu^3}$ is.
Also, for redshift $z$,
$$I_\nu\propto\nu^3 \propto\inv{(1+z)^3}$$
so intensity decreases with redshift. Finally:
$${I_\nu\over\eta^2}$$
is conserved along a ray, where $\eta$ is the index of refraction.
\subsection*{ The Blackbody }
A blackbody is the simplest source: it absorbs and reemits radiation with
100\% efficiency. The frequency content of blackbody radiation is given by
the {\it Planck Function}:
\def\ehv{e^{{h\nu \over kT}}}
$$B_\nu={h\nu\over\lambda^2}{2\over(\ehv-1)}$$
$$\boxed{B_\nu={2h\nu^3\over c^2(\ehv-1)}\ne B_\lambda}$$
\centerline{(The Planck Function for Black Body Radiation)}\par
Derivation:\par
The \# density of photons having frequency between $\nu$ and $\nu+d\nu$ has
to equal the \# density of phase-space cells in that region, multiplied by
the occupation \# per cell. Thus:
$$n_\nu d\nu={4\pi\nu^2d\nu\over c^3}{2\over\ehv-1}$$
However,
$$h\nu{n_\nu c\over 4\pi}=I_\nu=B_\nu$$
so we have it. In the limit that $h\nu\gg kT$:
$$B_\nu\approx{2h\nu^3\over c^2}e^{-{h\nu\over kT}}$$
\centerline{Wein tail}\par
If $h\nu\ll kT$:
$$B_\nu\approx{2kT\over\lambda^2}$$
\centerline{Rayleigh-Jeans tail}
Note that this tail peaks at $\sim {3kT\over h}$. Also,
$$\nu B_\nu=\lambda B_\lambda$$
\section*{ Lecture 2}
\subsection*{ Reiteration: Conservation of specific intensity }
Conservation of specific intensity told us the intensity collected by your
telescope is absolutely equal to the surface intensity emitted into the angle
leftrightarrowonding to your pixel on the sky. {\it Specific intensity is
distance independent}.
$1 m^2$ of sky emitted into angle $1\square " =$ specific intensity
measured by a $1m^2$ telescope pointed at a $1\square "$ pixel of sky.
\subsection*{ Units}
We have flux, flux density, surface brightness, and spectral energy
distribution to describe luminosity. When in doubt, look at the units.
Surface brightness, like specific intensity, is distance independent. It is
simply specific intensity integrated over frequency.
\subsection*{ Lenses}
If you look at something through a lens, the specific intensity of a point
is conserved. In the lens, the specific intensity may be greater, because
$I_\nu\over\eta^2$ is conserved (remember that $\eta$ is the index of
refraction of the medium), but once the light goes out again, even if the
object looks bigger, the specific intensity is the same. {\it This does not
violate conservation of energy because the light is being focused to
a smaller area.}\par
Now if something is {\it inside} the lens (say, a bowl of water), then
the lens bends light rays closer to each other, increasing the specific
intensity. Thus, the object is emitting/scattering higher density photons,
and appears more luminous, and the object also appears larger. This means
that there must be some places where the object, omitting the lens, would have
been visible, but now isn't.
\subsection*{ Blackbodies}
The CMB is the perfect blackbody because in the past, the surface of the
black body (the edge of the universe) was not allowed to leak out energy.
This begs the question:
does it matter what the boundary of the black body is made of?
The answer is: No. In the short term, the boundary may imperfectly reflect
a photon,
but then the resulting change in the temperature of boundary dictates that
it will tend to reemit the energy into the photon gas. Overall:
$$I_\nu I_{emitted}=I_\nu I_{absorbed}=B_\nu f_{abs}$$
However, $f_{emission}B_\nu\equiv I_\nu I_{emitted}$, so:
$$\boxed{f_{emission}=f_{abs}}$$
\centerline{(Kirchoff's Law)}\par
Note that Kirchoff's Law is true regardless of equilibrium.
\subsection*{ Fundamental equation of transfer}
The fundamental equation of transfer is governed by emission and extinction.
Extinction is brought about by absorption (which changes photon energy) or
by scattering (which does not). Examples of scattering are Thomson scattering
off of cold electrons, Rayleigh scattering in the atmosphere, and Line
scattering (reemission in a different direction).
An example of absorption is photoionization (where a photon ionizes an atom,
say by knocking off an electron).\par
\begin{itemize}
\item Absorption:\par
Let's say radiation $I_\nu$ passes through a region $ds$ of
absorption/scattering on its way to us. Then:
$$dI_\nu=-\alpha_\nu I_\nu ds$$
where $\alpha_\nu$ is the {\it extinction} coefficient (units of $cm^{-1}$).
We may compute $\alpha_\nu$ a couple different ways:
$$\alpha_\nu=\overbrace{n}^{\#\ density}
\overbrace{\sigma_\nu}^{cross\ section}
=\overbrace{\rho}^{mass\ density}\overbrace{\kappa_\nu}^{opacity}$$
Solving for intensity:
$$\begin{aligned}I_\nu(s)&=I_\nu(0)e^{-n\sigma_\nu s}\\
&=I_\nu(0)e^{-\tau_\nu}\\ \end{aligned}$$
where $\tau_\nu$ is the {\it optical depth} at $\nu$.
Optical depth is often computed as:
$$\tau_\nu=n\sigma_\nu s=N\sigma_\nu$$
where $N$, the {\it column density}, is in $cm^{-2}$ and is the \# of
extinguishers per unit area.
Similarly,
$$\tau_\nu=\rho\kappa_\nu s=\Sigma\kappa_\nu$$
where $\Sigma$ is the mass surface density.
$$\tau_\nu\begin{cases}\ll 1 &optically\ thin\\
\gg 1 &optically\ thick\end{cases}$$
\def\mfp{\lambda_{mfp,\nu}}
The {\it Mean Free Path} is given by: $\mfp=\alpha_\nu^{-1}=\inv{n\sigma_nu}
=\inv{\rho K_\nu}$. Thus:
$$\tau_\nu={s\over\mfp}$$
That is, the optical depth is the number of mean-free-paths deep a medium is.
For Poisson processes, the probability of absorption is given by:
$$P(n)={e^{-{s\over\mfp}}\left({s\over\mfp}\right)^n\over n!}$$
Therefore:
$$I_\nu(s)=I_\nu(0)e^{-\alpha_\nu s}$$
\item Emission:\par
If $j_\nu $ is the emissivity, then the contribution of the emissivity of
a medium to the flux is:
$$dI_\nu=j_\nu ds$$
\item Emission and Extinction together:
$$\boxed{{dI_\nu\over ds}=j_\nu-\alpha_\nu I_\nu}$$
\centerline{(Fundamental Equation of Transfer)}\par
It is often convenient to express this in terms of optical depth.
Dividing by $\alpha_\nu$ and recognizing $d\tau_\nu = ds \alpha_\nu$:
$$\begin{aligned}{dI\nu\over d\tau_\nu}&={j_\nu\over\alpha_\nu}-I_\nu\\
&=S_\nu-I_\nu\\
\end{aligned}$$
where $S_\nu$ is a ``source function''. In general,
$$S_\nu\eval{scattering}\propto\int{I_\nu d\Omega}$$
There is a formal solution for $I_\nu$. Let's define
$\tilde I\equiv Ie^{\tau\nu}$ and $\tilde S\equiv Se^{\tau\nu}$. Then:
$${d\tilde I\over d\tau_\nu}=\tilde S$$
$$\tilde I(\tau _\nu)=\tilde I(0)+\int_0^{\tau_\nu}{\tilde Sd\tilde\tau_\nu}$$
$$\boxed{I_\nu(\tau_\nu)=\overbrace{I_\nu(0)e^{-\tau_\nu}}^{atten\ bg\ light}
+\overbrace{\int_0^{\tau_\nu}{S_\nu(\tau_\nu^\prime)
\underbrace{e^{-(\tau_\nu-\tau_\nu^\prime)}}_{self-absorption}
d\tau_\nu^\prime}}^{glowing\ medium}}$$
If $S_\nu$ is constant with $\tau_\nu$, then:
$$I_\nu(\tau_\nu)=I_\nu(0)e^{-\tau_\nu}+S_\nu(1-e^{-\tau_\nu})$$
That second term on the righthand side can be approximated as $S_\nu\tau_\nu$
for $\tau_\nu\ll 1$, since self-absorption is negligible. Similarly, for
$\tau_\nu\gg 1$, it may be approximated as $S_\nu$.
The source function $S_\nu$ is everything. It has both the absorption and
emission coefficients embedded in it.
\end{itemize}
\def\eboltz{e^{{-h\nu _0 \over kT}}}
\section*{ Lecture 3}
For a sphere to be a black body, it requires that $f_{abs} = f_{emis} = 1$.
However it can still be Planckean if $0<f_{abs}=f_{emis}\le 1$.
\subsection*{ Local Thermodynamic Equilibrium (LTE)}
Local Thermodynamic Equilibrium means
$$S_\nu=B_\nu(T)$$
where $T$ is {\it local}.
Take a sphere at surface temp $T$, with some gas (matter) inside it. Allow
to come to thermal equilibrium. Inside the sphere,
you see a Planckean spectrum ($I_\nu = B_\nu$). Now suppose you take a box of
gas (it is both emissive and absorbent) and shoot rays of photons through
that box suffer some absorption:
$$dI_\nu = -\alpha _\nu ds I_\nu$$
But
those photons also pick up some intensity:
$$dI_\nu = +j_\nu ds$$
But since the photons
should not pick up energy going through the box (everything is at the same
temperature),
$$S_\nu\equiv{j_\nu\over\alpha_\nu}=I_\nu=B_\nu$$
Now suppose you let all the photons out of this sphere. Those photons will
no longer be in thermal equilibrium with the gas. Suppose we magically fix
the temperature of the gas at this point. The source function will remain the
same (it will still be the case that $S_\nu = B_\nu$) because the source
function {\it is a property of the matter alone} (the absorptive and emissive
properties of it). However, $I_\nu\ne B_\nu$.\par
Suppose we look along a column of this gas. At each point, the source
function will be: $S_\nu=B_\nu(T)$. Therefore, $I_\nu$ along that column
will be:
\def\np{{\nu^\prime}}
$$I_\nu=\int_0^{\tau_\nu}{S_\nu(\tau_\np)e^{-(\tau_\np-\tau_\nu)}d\tau_\np}$$
\subsection*{ Einstein Coefficients}
Derivation identical to Rybicki's. We should memorize these.\par
These coefficients govern the interaction of radiation with discrete energy
levels. Say we have 2 energy levels with a difference $\Delta E=h\nu_0$.
There is some uncertainty associated with $\nu$, but we'll say it's small for
now.\par
There are 3 coefficients:\par
\begin{itemize}
\item $\ato$ governs decay from 2 to 1, and is the transition
probability per
unit time. The probability of spontaneous
de-excitation and release of photon is Poisson-distributed with mean rate
$\ato$. So $\ato^{-1}$ is the mean lifetime of the excited state. e.g.
For $H_\alpha$ (n=3 to n=2): $\ato\approx 10^9 s^{-1}$.
\item $\bot$ governs absorptions causing transitions $1\to2$.
The transition probability per unit time is $\bot J_\nu$, where $\bot$ is
the probability constant, and $J_\nu$ is:
$$J_\nu \equiv {\int{I_\nu d\Omega} \over 4\pi}$$
It depends on $I_\nu$ (the intensity), but it does not depend on
direction, so we integrate over all angles. The $4\pi$ is a normalization
constant which makes $J_\nu$ the mean intensity, instead of the total intensity.
However, we have to remember that there are uncertainties in the energy-level
separations. $\phi(\nu)\equiv$ is called the line profile function. It
describes
some (maybe gaussian) distribution of absorption around $\nu_0$ (the
absorption frequency), and is subject to the requirement that:
$$\int_0^\infty{\phi(\nu)d\nu}=1$$
Say that $\Delta\nu$ is the width
of the distribution around $\nu_0$. $\Delta \nu $ is affected by many factors:
$\ato$ (the natural, uncertainty-based broadening of at atom in isolation),
$\nu_0{V_T\over c}$ (the thermal, Doppler-based broadening), and
$n_{coll}\sigma_{coll}v_{rel}$
(collisional broadening, a.k.a. pressure broadening).
So really, the transition probability per unit time is:
$$R_{ex}^{-1}=\bot\int_0^\infty{J_\nu\phi(\nu)d\nu}\approx\bot\_J$$
\item $\bto$ governs stimulated emission. In this example, we are in energy
state 2, and an incoming photon causes a transition to energy level 1 and the
emission of 2 photons. The transition per unit time is $\bto\_J$.
\end{itemize}
\subsection*{ Einstein Relations among coefficients}
Assume we have many atoms with 2 energy states, and $n_1$ is the \# density
in state 1, ditto for $n_2$. Assume we are in thermal, steady-state
equilibrium, so:
$$n_1\bot\_J=n_2\ato+n_2\bto\_J$$
This is because as many atoms need to be
going from energy state 1 to 2 as visa versa.
A second relation is:
$\_J = {n_2\ato\over n_1\bot-n_2\bto}$.
Using that ${n_2\over n_1}={g_2\over g_1}\eboltz$:
$$\_J={{\ato\over\bto}\over{g_1\bot\over g_2\bto}\eboltz-1}$$
In thermal equilibrium $J_\nu=B_\nu$:
$$\begin{aligned}\_J&\equiv\int_0^\infty{J_\nu\phi(\nu)d\nu}\\
&=\int_0^\infty{B_\nu\phi(\nu)d\nu}\\
&\approx B_\nu(\nu_0)\\
&={2h\nu_0^3\over c^2(\eboltz-1)}\\ \end{aligned}$$
Combining this with $\_J$ earlier, we get:
$$\boxed{g_1\bot=g_2\bto}$$
\centerline{and}
$${\ato\over\bto}={2h\nu^3\over c^2}$$
\subsection*{ Rewriting $j_\nu, \alpha_\nu $ in terms of Einstein coeffs}
In a small volume $dV$:
$$\begin{aligned}j_\nu&\equiv{dE\over dt\,dV\,d\nu\,d\Omega}\\
&={h\nu_0\ato n_2\phi(\nu)\over4\pi}\\ \end{aligned}$$
We can express $\alpha_\nu$ in terms of the Einstein coefficients. The
excitation probability per time is $n_1B_{12}\_J$, and
the energy lost in crossing the small volume
$\propto n_1\bot{I_\nu d\Omega\over4\pi}\phi(\nu)d\nu$
(it is the probability per time per volume of going $1\to2$ by absorbing
$I_\nu$ from
a cone of solid angle $d\Omega$ and frequency range $[\nu,\nu+d\nu]$). Thus,
the energy is given by:
$$\begin{aligned}E&=n_1\bot{I_\nu d\Omega\over4\pi}\phi(\nu)d\nu h\nu dt\,dV\\
&=\alpha_\nu I_\nu ds\,dt\,d\Omega\,dA\,d\nu\\ \end{aligned}$$
Recognizing that $dV=dA\,ds$:
$$\alpha_\nu={n_1\bot\phi(\nu)\over4\pi}h\nu$$
Correcting for stimulated emission, we get:
$$\boxed{\alpha_\nu={(n_1\bot-n_2\bto)\phi(\nu)h\nu\over4\pi}}$$
\section*{ Lecture 4 }
\subsection*{ Estimating Cross-Section}
The absorption coefficient, written in terms of Einstein constants is:
$$\alpha_\nu={n_1\bot\phi(\nu)\over4\pi}h\nu=n_1\sigot$$
Thus, the cross-section of an atom for absorption of a photon is:
$$\sigot={\bot\phi(\nu)h\nu\over4\pi}$$
To estimate $\bot$, we use the fact that, ignoring g's, $\bot\sim\bto$,
and ${\ato\over\bto}={2h\nu^3\over c^2}$. Then using the approximation that
that $\phi(\nu)\sim\inv{\Delta\nu}$, we get:
$$\sigot\sim{\ato\over\left({2h\nu^3\over c^2}\right)}
\inv{\Delta\nu}$$
$$\boxed{\sigot\sim{\lambda^2\over8\pi}{\ato\over\Delta\nu}}$$
In a single atom, $\Delta\nu\sim\ato$, so $\sigot\sim{\lambda^2\over8\pi}$.
\subsection*{ Order of Magnitude Interaction of Radiation and Matter}
\subsection*{Energy Levels}
\begin{itemize}
\item Electronic Transitions:\par
We'll start with the Bohr atom. We begin by quantizing angular momentum:
$$m_ev_ea_0=n\hbar$$
If we balance the force required to keep the $e^-$ in a circular orbit
with the electric force:
$${m_ev_e^2\over a_0}={Ze^2\over a_0^2}$$
$$a_0={\hbar^2\over m_ee^2Z}\approx0.52{\AA\over Z}$$
A {\it Rydberg} is the energy required to ionize an H atom from the ground
state. It is $\sim13.6eV$. We can estimate it by integrating the electric
force from $r=a_0$ to $r=\infty$, but in reality, there is another factor of
2:
$$\boxed{Rydberg={Ze^2\over2a_0}={Z^2e^4m_e\over2\hbar^2}=13.6\cdot Z^2eV}$$
\item Fine Structure:\par
Fine Structure comes from the interaction of the magnetic moment of the $e^-$
with the a $\bfield$ caused by the
Lorentz-transformed Coulomb field of the proton (generated by the $e^-$'s
motion). The
energy of a dipole interaction is $E=\vec\mu\cdot\bfield$, so we'd expect
that:
$$\Delta E\sim\mu B$$
To estimate B: $B\sim{Ze\over a_0^2}{v\over c}$, and ${v\over c}\sim
{e^2\over\hbar c}=\alpha=\inv{137}$ ($\alpha$ is the fine structure constant):
$$B\sim{Ze^3\over\hbar ca_0^2}$$
Estimating $\mu$: The $\bfield$ of a dipole goes as $B_{di}\sim{\mu\over r^3}$,
so $\mu\sim B_e\eval{r_e}r_e^3$, where $r_e$ is the classical $e^-$ radius.
Estimating that the rest mass energy of the $e^-$ should be about the
electrostatic potential energy left in the $e^-$, $m_ec^2\sim{e\over r_e}$:
$$r_e\sim{e^2\over m_ec^2}$$
We can estimate $B_e$ by reverting to Maxwell's equation:
$$\dcb={4\pi J\over c}$$
$${B_e\over2\pi r_e}={4\pi\over c}{I\over4\pi r_e^2}$$
Again, we estimate that $I\sim{e\over t_{spin}}$, and because the electron
spin is quantized, $\hbar=m_er_e^2{2\pi\over t_{spin}}$.
After some algebra, we get that:
$$\mu_e={e\hbar\over2m_ec}$$
\centerline{(Bohr magneton for $e^-$)}
$$\mu_p={Ze\hbar\over2m_pc}$$
\centerline{(Bohr magneton for nucleus)}
Getting back to the energy:
$$\begin{aligned}\Delta E&\sim{e\hbar\over2m_ec}{Ze\over a_0^2}\alpha\\
&\sim Z^4\alpha^2\cdot Ryd\\ \end{aligned}$$
\item Hyperfine Structure:\par
Instead of using the Bohr magneton, we use the intrinsic magnetic moment
(spin) of the nucleus:
$$B\eval{p}\sim{\mu_p\over a_0^3}\sim B_{fine}{m_e\over m_p}$$
Thus:
$$\Delta E\sim\Delta E_{fine}{m_e\over m_p}$$
Note that Fine and Hyperfine are magnetic dipole transitions. $e^-$ level
transitions are {\it electric} dipole transitions. Magnetic dipole transitions
are generally weaker.
\item Vibrational Transitions in Molecules:\par
Our general technique with vibrational transitions is to model them as
harmonic oscillators. Thus, they should have the characteristic harmonic
energy series:
$$E_n=(n+\hf)\hbar\wz$$
For a harmonic oscillator, $\wz=\sqrt{k\over m}$. We estimate that since
the force for a spring is $k\cdot x$, and that force should be about the
Coulomb force on electrons. If we say that atoms stretch with respect to
each other about a Bohr radius:
$$ka_0\sim{e^2\over a_0^2}$$
$$\Delta E\eval{vib\atop trans}\sim Ryd\cdot\sqrt{m_e\over A\cdot m_p}$$
where A is the atomic mass \# of our atoms.
\item Rotational Transitions in Molecules:\par
The thing to remember is that angular momentum comes in units of $\hbar$.
\end{itemize}
\subsection*{ Damped Simple Harmonic Oscillator}
We can model $e^-$ and their atoms as a lattice of springs connecting $e^-$
to fixed points. Say that we send a plane wave at these springs that
looks like:
\def\eikrwt{e^{i(\vec k\vec r-wt)}}
$$\ef=E_0\eikrwt$$
We'll say that the displacement of $e^-\ll{2\pi\over k}$. The equation of
motion for a single electron is then:
$$\ddot x+\gamma\.x+\wz^2x={-eE_0\eikrwt\over m_e}$$
where $\gamma$ is our dampening factor. Note that $\bfield$ is absent
here; we're neglecting it because it is small for
reasonable energies. It turns out this
equation has the steady-state solution:
$$x={-e\over m_e}{\left((\wz^2-\omega^2)+i\omega\gamma\right)\over
\left((\wz^2-\omega^2)^2+(\omega\gamma)^2\right)}E_0\eikrwt$$
The limiting cases of this equation explain many phenomena. For example:
$\gamma=0$ (loss-less propagation).\par
In this case, our solution looks like:
$$x={-e\over m_e}{E_0\eikrwt\over(\wz^2-\omega^2)}$$
From this we can use the dispersion relation to relate $\omega$ (frequency) and
$k$ (phase).
\subsection*{ The Dispersion Relation}
Let's solve Maxwell's equations. Recall that $\vec J$ is the current density:
$$\begin{aligned}\vec J&=-n\cdot e\cdot\.x\\
&={-ne(-i\omega)(-eE_0\eikrwt)\over m_e(\wz^2-\omega^2)}=\sigma\ef\\ \end{aligned}$$
where $\sigma\equiv conductivity={-ne^2i\omega\over m_e(\wz^2-\omega^2)}$, and
n is the \# density of electrons.
So on to Maxwell's equations:
$$\begin{aligned}\dce&=-{1\over c}{\partial\bfield\over\partial t}\\
ik\times E&={i\omega B\over c}\\ \end{aligned}$$
$$\begin{aligned}\dcb&={4\pi\vec J\over c}+{1\over c}{\partial\ef\over\partial t}\\
-ik\times B&=\left({4\pi\sigma\over c}-{i\omega\over c}\right)E\\ \end{aligned}$$
Combining these two equations we get:
$$\boxed{\left({ck\over\omega}\right)^2=1-{4\pi ne^2\over
m_e(\omega^2-\wz^2)}}$$
This is our dispersion relation. The plasma frequency is defined as:
$$\omega_p^2\equiv {4\pi ne^2\over m_e}$$
and the index of refraction is:
$$\eta\equiv{ck\over\omega}$$
Rewritten in these terms, our dispersion relation in plasma is:
$$\boxed{\eta^2=1-{\omega_p^2\over\omega^2}}$$
\section*{ Lecture 5 }
\def\lya{Ly\alpha}
\subsection*{ Einstein A's for $\lya$}
$\ato$ is a measure of the probability of decay per unit time, so
$\ato^{-1}\sim lifetime$. This should be about
equal to the energy of the electron state divided by the average power radiated
by an electron being accelerated:
$$\ato^{-1}\sim{E\over P}\sim{\hbar\omega_0\over{2\over3}{e^2\ddot x^2
\over c^3}}
\sim{3\hbar\omega_0c^3\over2(e\ddot x)^2}$$
Now $e\cdot\vec x=\vec d$ (the electric dipole moment) and
$\ddot x\sim\omega_0^2x$ for a spring, so:
$$\ato^{-1}\sim{3\hbar\wz c^3\over2d^2\wz^4}$$
$$\boxed{\ato\sim{2d^2\wz^3\over3\hbar c^3}}$$
For H: $d\sim ea_0$ and $\lambda_\lya=1216\AA$ (and don't forget $\omega=2\pi\nu$) so:
$$\ato\sim5\e8s^{-1}$$
\subsection*{ Magnetic Dipole for $\lya$}
The magnetic dipole of an electron is:
$$\mu_e={e\hbar\over m_ec}$$
Thus we can estimate the ratio of $\ato$ for magnetic dipole transitions to
that of electric dipole transitions:
$${\ato\eval{mag}\over\ato\eval{elec}}\sim\left({\mu_e\over d}\right)^2
\sim\left({e^2\over\hbar c}\right)^2\sim\alpha^2$$
This tells us that the magnetic dipole states (that is, fine and hyperfine
states) are longer lived than electric dipole states by a factor of $\alpha^2$.
$${\ato\eval{21cm}\over\ato\eval{Ly\alpha}}\sim\alpha^2
\left({1216\AA\over21cm}\right)^3$$
$$\ato\eval{21cm}\sim6\e{-15}s^{-1}$$
The actual value is $2.876\e{-15}s^{-1}$.
\def\mfe{\mathfrak{E}}
\subsection*{ Electric Quadrupole}
If one is nearby a rotating quadrupole, one sees the $\mfe$ (electric)
field rotating rigidly.
However, from far away, there are kinks in the field, resulting in a retarded
potential. The radiation nearby goes as $r_{near}\sim\lambda$. For a monopole,
the electric field is $\mfe\sim{q\over r^2}$. For a dipole, it is
$\mfe={q\over r^2}
{s\over r}$, where s is the charge separation. For a quadrupole:
$$\mfe={q\over r^2}\left({s\over r}\right)^2$$
Since $P\propto \mfe^2$, the ratio of the powers emitted by a
quadrupole vs. a dipole should be:
$${P_{quad}\over P_{di}}\sim\left({s\over r}\right)^2
\sim\left({s\over\lambda}\right)^2$$
An acoustic analogy: a kettle whistle is a monopole, a
guitar string is a dipole, and a tuning fork (with its two out-of-phase
prongs) is a quadrupole.\\
Anyway, since $\ato\sim{P\over E}$,
$$\boxed{{\ato\eval{quad}\over\ato\eval{di}}
\sim\left({s\over\lambda}\right)^2}$$
Thus $28\mu m$, the lowest quadrupole rotational transition of
$H_2$, should have an $\ato$ of about:
$$\ato\eval{28\mu m}\sim\ato\eval\lya\left({s\over\lambda_{H_2}}\right)^2
\left({\lambda_\lya\over \lambda_{H_2}}\right)^3
\sim\ato\eval\lya\left({a_0\over 28\mu m}\right)^2
\left({1216\AA\over 28\mu m}\right)^3
\sim7\e{-11}s^{-1}$$
The actual value is $3\e{-11}s^{-1}$.
\subsection*{ Radio Recombination Lines}
In HI, the $n=110\to n=109$ transition has a wavelength of 6 cm. We can
estimate its $\ato$:
$$\ato\eval{6cm}\sim\ato\eval{Ly\alpha}
\underbrace{\left({1216\AA\over6cm}\right)^3}_{change\atop in\ \lambda}
\underbrace{\left({a_{110}\over a_0}\right)^2}_{change\atop in\ atom\ size}$$
\def\bra#1{\langle #1|}
\def\ket#1{|#1\rangle}
This presents the question of which dipole moment to use. It turns out
we must use $\bra{i}\vec k\cdot\vec r\ket{f}$.
\subsection*{ Back to $\sigma$}
$$\sigot\eval{line\atop center}\sim{\lambda^2\over8\pi}{\ato\over\Delta\nu}$$
Now $\Delta\nu\sim\nu$ for doppler broadening, and $\ato\sim\nu^3$, so for
electric and magnetic dipole transitions:
$$\sigot\sim\lambda^0$$
So the cross-section for these transitions does not depend on wavelength.
\subsection*{ Interaction of Radiation with Grains}
In general, we will be talking about a plane wave of wavelength $\lambda$
which is incident upon a particle (grain) of radius a. The cross-section
for absorption, scattering, and emission will all be proportional to the
physical cross-section of the grain, with some {\it absorption efficiency}
Q:
$$\sigma_i=Q_i\pi a^2$$
Kirchkoff's Law requires that $Q_{emit}=Q_{abs}$. If $a\gg\lambda$, then
\def\qscat{Q_{scat}}
\def\qabs{Q_{abs}}
we have the geometric optics limit, and $\qscat+\qabs\sim1$. In fact,
Babinet's Principle says:
$$\boxed{\qscat+\qabs=2}$$
The proof of this goes as follows: suppose we have an infinite plane wave
focused by an infinite lens onto a point on a wall. The power pattern
should be a delta function at that point on the wall. Now suppose you
place a screen with an aperture of diameter $a$ between the plane wave
and the lens. We should now see an interference pattern on the wall. Call
the power incident on a point on the wall $P_1$. Now put in a new aperture
which is the exact compliment of our previous one (it is a scattering
body of diameter $a$), we should see a new power at our point on the wall:
$P_2$.
However, the sum of waves incident on the wall under these two apertures
should be the same as the wave from the sum of the apertures, which was
a delta function. Thus:
$$P_1=P_2$$
The first aperture (the slit) represented the scattering power from
diffraction alone $(\qscat=1)$, and the second represented the absorbed
power. The sum of these two powers, for everywhere but the true focus
point, is actually twice the incident power, and since $P_1=P_2$, we
get:
$$\qscat+\qabs=2$$
Note that if $\qscat>1$, then the object is ``shiny'': more light gets
diffracted and less gets absorbed. Thus, although $\qscat$ changes,
the sum remains the same.
\section*{ Lecture 6 }
\def\eb{e^{h\nu \over kT}}
\subsection*{ Flat Blackbody disk:}
$$\begin{aligned}\nu F_\nu&\propto\nu^4\int_{r_i}^{r_0}{2\pi r\,dr\over\eb-1}\\
&\propto \nu^3\int_{r_i}^{r_0}{r\,dr\over
e^{h\nu\over kT}({r\over R_*})^{3\over 4}-1}\\ \end{aligned}$$
Define $x \equiv {h\nu\over kT_*}({r\over R_*})^{3/4}$. Then:
\def\hnkt{{h\nu \over kT_*}}
\def\tq{{3\over 4}}
$$\nu F_\nu \propto \nu^4\int{{\hnkt ({r_i\over R_*})^\tq}^{\hnkt ({r_o\over
R_*})^\tq}{x^3dx\over e^x - 1}}$$
We are free to choose $\nu$, so we'll choose it such that:
$$\nu_0\sim{kT_*\over h}({R_*\over r_0})^\tq\ll\nu\ll{kT_*\over h}
({R_*\over r_i})^\tq\sim\nu_i$$
Then the integral simplifies to:
$$\nu F_\nu \propto \nu^{4\over 3}\int_{x\ll 1}^{x\gg 1}{x^3dx\over e^x-1}$$
This is, on the whole, insensitive to exact values on the bounds of the
integral, so:
$$\nu F_\nu \propto \nu^{4\over 3}$$
Thus, if we are plotting $\nu F_\nu$ vs. $\nu$ (like on the homework), we
see a flattening of the spectrum for the blackbody disk because of the region
where $\nu F_\nu \propto \nu^{4\over 3}$.
\subsection*{ Plane waves through a lens onto a backdrop}
We are considering a case of sending an infinite plane wave through an
infinite lens with focal length $f$ onto a backdrop which is distance $f$
away. Next, we consider what happens if we have: (a) an occulting object
at the center of the lens, (b) the exact opposite of that object--an
aperture at that point. We'll get diffraction patterns on our backdrop in
both of these cases. What is interesting is that the sum of the apertures
(in our case, an infinite aperture minus a spot plus that spot) should also
sum the diffraction patterns. The diffraction pattern for an infinite,
unblocked aperture is just a delta function (everything focused at the
focal point). Thus the fringe patterns for each of the partially blocked
apertures must be the same, but $180^\circ$ out of phase. Of course,
the (infinite aperture minus a spot) contains a delta function in addition
to its diffraction pattern.\par
\subsection*{ Small Grains}
Now let's consider the case that this spot (a small object obstructing a
plane wave) is small, so that $a \ll \lambda$. This is called the ``Rayleigh
Limit''. In this case, $Q_{scat} \ll 1$ and $Q_{em} = Q_{abs} \ll 1$. If
\def\qabs{Q_{abs}}
\def\qscat{Q_{scat}}
\def\qemis{Q_{emis}}
we were to graph $\qabs$ vs. $\lambda$, we'd get something flat ($= 1$) out to
$2\pi a$, after which, $\qabs$ would decrease as $(\inv{\lambda})^\beta$, where
$\beta\eval{abs} = [1-3]$. On the other hand, graphing $\qscat$ vs. $\lambda$
, we get that after $2\pi a$, $\qscat$ drops as $(\inv{\lambda})^4$.
Why does $Q$ decrease as $a\over \lambda$?\par
\begin{itemize}
\item Let's consider the case of emitting with a dipole antenna. For a
region close to the antenna (the near zone, of order $\lambda$),
$P_{rad}\propto E^2$, and at the edge of the near zone,
$E\propto{a\over\lambda}$. Since $P_{rad}\propto\qemis\propto\qabs$,
$$\qabs\propto\left({a\over\lambda}\right)^2$$
\item Here's another crude way of looking at it:
if you're in a boat that's small compared
to the size of a wave coming at it, you aren't going to do anything to that
wave (you won't scatter, everything transmits).
\item Another way of looking at it:
the damped simple harmonic oscillator. Recall that:
$$\sigma_{abs} = {4\pi e^2\over m_e c}{w\gamma \over \left[(w_0^2-w^2)^2 +
(w\gamma)^2\right]}$$
If $w \ll w_0$, then:
$$\sigma_{abs} \to {4\pi e^2\over m_e c}{w^2\gamma \over w_0^4} \propto w^2$$
Thus, $\qabs \propto \inv{\lambda^2}$.
\end{itemize}
Finally, there is Mie Theory, which states that if $\eta = n +ik$, where
$\eta$ is the complex index of refraction, then you can express $\qabs$ and
$\qscat$ in terms of the size parameter $x \equiv {2\pi a\over \lambda}$.
For this derivation that Mie did, $n, k$ are called ``optical constants''. This
is a bad name, because both of these are actually functions of $\lambda$.\par
Now we look at the handout Eugene gave us (Chiang et al, 2001, ApJ, 547, 1077).
Notice on the $\qabs$ vs. $\lambda$ plots, in addition to the decay we
described, there are ``bumps and wiggles''. These are characteristic of the
resonances of the systems (e.g. they leftrightarrowond to a rotational mode, etc.).
The varying lines on each graph are for different sized particles. Notice the
characteristic Rayleigh Limit for small particles. \par
\def\qext{Q_{ext}}
There's another graph about how extinction $\qext = \qabs + \qscat$ goes as
the size parameter is changed. There is a large ``hump'' where $\qext$ goes to
about 4. It can do this (we'd said it couldn't go above 2) because we are not
yet in the geometric optic limit. Notice that on this big hump, there is a
region where increased wavelength causes increased extinction. This is the
process which causes ``blue moons''. If the size of particles in the atmosphere
is just right, it will pass blue wavelengths while extinguishing red.\par
\subsection*{ Some special results}
\def\sabs{\sigma_{abs}}
\begin{itemize}
\item Crystalline dielectrics: $\qabs \propto {a\over \lambda^2}$ (for
$\lambda \gg a$). Then:
$$\alpha_\nu \eval{abs} = n_d\sabs = n_d\pi a^2\qabs
\propto {a^2\over \lambda^2}$$
Now what we measure in the field is $\tau$, the
optical thickness. However, $\tau_\nu = \sum{K_\nu}$, where $K_\nu =
{\sabs \over m_{particle}} \propto a^0$. This is how the mass of
particles can measured. Then $\qscat \sim ({a\over \lambda})^4$, like
Rayleigh scattering.
\item In general: $j_\nu\eval{emission} = \alpha_\nu \cdot B_\nu(T)$.
Then:
$$j_\nu\eval{scattering}(\^n) = n_d(\qscat\pi a^2)\int{I_\nu(\^n)
F(\^n-\^n^\prime)d\Omega^\prime}$$
The term $F(\^n - \^n^\prime)$ is called the ``scattering phase function'', and
is used to add up all of the incoming paths of light, taking into account their
relative phases. $n_d$ is the \# density of scattering grains. For small
enough grains ($a\ll \lambda$), F is independent of the properties of the
material the grains are made of:
$$F = {1+\cos^2\theta\over 2}$$
where $\theta$ is the angle from the propagation direction of the incident beam.
This gives us a characteristic ``dog bone'' scattering pattern. Small grains
are (to within a factor of 2) isotropic scatterers. The factor of 2 is the
dog bone pattern. Note that the ``missing half'' at right angles to the
propagation direction is the portion of incident light which had no polarization
component which aligns with the characteristic polarization which must exist
for light detected at a right angle from a scattering body.
\end{itemize}
\section*{ Lecture 7 }
\subsection*{ Increasing Grain Size}
We return to the model in which an infinite plane wave passes through an
aperture, is focused by an infinite lens, and shines on a wall. In this
model, as the slit aperture widens (a increases), then the diffraction
pattern narrows. Thus, for larger grain sizes, there is more forward
scattering than in other directions. The fitting formula for the power
pattern for large grains is:
$$F(\theta)={1-g^2\over1+g^2-2g\cos\theta}$$
where $g\equiv\mean{\cos\theta}={\int{F\cos\theta d\Omega}\over
\int{Fd\Omega}}$. Note that this formula fails for $\theta=100^\circ$. If
$g=1$, then we have isotropic scattering, and as $g\to1$, $F(\theta)$ peaks
increasingly in the $\theta=0$ direction (it is increasingly
``forward throwing'').
\subsection*{ Forward Scattering}
Forward scattering can actually increase the intensity of light in some areas
over if there were no scattering at all.
If particles are smaller that the wavelength of light, there is isotropic
scattering. For larger particles, the power is more concentrated in the
perfectly forward and backward directions. This is why, where there is fog,
you dim your headlights. The larger scattering particles in the fog actually
increases the intensity of light reflected back at you and at oncoming cars.
\subsection*{ Collisional Excitation Cross-sections}
The Einstein analog:
$$\overbrace{A}^{low\ E\ particle} + \overbrace{B_{fast}}^{high\ E\ e^-}
\to \overbrace{A^*}^{excited} + B_{slow}$$
So the Rate of Excitations $R_{ex}$ is given by:
\def\rex{R_{ex}}
\def\vrel{v_{rel}}
$$\rex = n_An_B\sigma_{12}f(\vrel)\vrel$$
Suppose we have some distribution of relative velocities given by $f(v)dv$,
where $f$ is the fraction of collisions occurring with relative velocities
$[\vrel, \vrel +dv]$. Then:
$$\rex = n_An_B\int_0^{\infty}f(v)dv\sigot(v)v$$
$$=n_An_B \mean{\sigot v}$$
\def\qot{q_{12}}
\def\qto{q_{21}}
$$=n_An_B\qot$$
where $\qot$ is the ``collisional rate coefficient'' $[cm^3s^{-1}]$. Then the
Rate of de-excitation is given by:
$$R_{deex} = n_An_B\int_0^\infty{f(v)v\,dv\sigma_{21}(v) = n_A^*n_B\qto}$$
We recognize now that $\sigot(v)n_An_Bf(v)dv\,v$ is the rate of excitations of
A using B moving at relative velocity $v$. If we have detailed balance,
then this has to be the same as the rate of de-excitation
$n_A^*n_Bf(v^\prime)v^\prime\sigto(v^\prime)$.
$$\overbrace{\hf m_rv^2}^{center\ of\ mass\ E} = hv_{12} + \hf m_rv^{\prime2}$$
Where $m_r$ is the reduced mass $m_Am_B\over m_A+m_B$. However many $B_{slow}$
are created by collisional excitation, the same number are used for the
reverse de-excitation. This is {\bf detailed balance}.\par
Second, assuming particles have a {\bf Maxwellian} velocity
distribution:
$$\boxed{f(v)=4\pi\left({m_r\over 2\pi kT}\right)^{3\over 2}v^2
e^{-m_rv^2\over 2kT}}$$
\centerline{(Maxwellian velocity distribution)}
In thermal equilibrium,
$${n_A^*\over n_A} = {g_2\over g_1}e^{-h\nu_{21}\over kT}$$
Now, assuming detailed balance (with $v dv=v^\prime dv^\prime$) and thermal equilibrium,
$$n_An_Bf(v)dv\,v\sigot=n_A^*n_Bf(v^\prime)dv^\prime v^\prime \sigto$$
\def\emvkt{e^{-m_rv^2\over2kT}}
\def\emvpkt{e^{-m_rv^{\prime2}\over2kT}}
\def\ehvkt{e^{-h\nu_{21}\over2kT}}
$$\sigot v^2\emvkt = {g_2\over t_1}\ehvkt v^{\prime2}\emvpkt v^\prime
dv^\prime\sigto$$
$$\sigot dv\,v^3 \emvkt = {g_2\over t_1}\ehvkt \ehvkt \emvkt v^{\prime3}
dv^\prime \sigto$$
$$\boxed{g_1v^2\sigot(v) = g_2v^{\prime2}\sigto(v^\prime)}$$
This is the ``Einstein analog''.\par
For a specific case, $B=e^-$, $A=$ion with bound electron.
\begin{itemize}
\item Incident electron has kinetic energy $>h\nu_{21}$.
$$\hf m_rv^2 \approx \hf m_ev^2 > h\nu_{21}$$
\item Coulomb focusing gives $\inv{v^2}$ cross-section.
\end{itemize}
We want to know how far away an electron with $v$ can be aimed
and still hit the $a_0$ radius cloud around the ion. This is $b$, the
{\bf impact parameter}. Our collision cross-section $=\pi b^2$. Our
angular momentum is conserved, so
$$m_ev\,b=m_ev_fa_0$$
We know that $v_f^2 = v^2 + v_\perp^2$, where $v_\perp$ is the velocity
$\perp$ to the original electron velocity. This is a result of it falling
toward the ion. Then:
$$\hf m_ev_\perp^2 \sim {Ze^2\over a_0}$$
$$v_f^2 = v^2 + {Ze^2\over m_ea_0}$$
$$b={a_0v_f\over v}$$
$$\pi b^2 = {\pi a_0^2\over v^2}\left[v^2+{Ze^2\over m_ea_0}\right]$$
$$= \pi a_0^2\left[1+\underbrace{Ze^2\over m_ev^2a_0}_{Coulomb\ focusing\atop
factor}\right]$$
Generally, the Coulomb focusing factor $>1$ because we want to excite, not
ionize. $a_0={\hbar^2\over Ze^2m_e}$, so:
$$\pi b^2 = {\pi\hbar^2\over Z m_ev^2}$$
$$\sigot = {\pi\hbar^2\over Z m_e^2v^2}
\overbrace{\left(\Omega(1,2)\over
g_1\right)}^{quantum\ mechanical\atop correction\ factor}$$
$\Omega$ is the ``collisional strength'', and generally is 0 below the
$v$ threshold, goes to 1 at the threshold, and decreases for increasing
$v$, with some occasional spikes. Generally, it is of order 1, with some
slight temperature dependency.
$$\qot=\mean{\sigot v} \propto \mean{\inv{v}} \propto \inv{\sqrt{T}}$$
\begin{itemize}
\item 2000 K gas. $v_{term} \sim \sqrt{\gamma kT\over m}$, so
$v\sim \sqrt{2000\over 100}42\cdot 1{km\over s} \approx 160{km\over s}$. Then
$$\sigot \sim 10^{-14}cm^2\left({\Omega(1,2)\over g_1}\right)$$
$$\sigot\eval{osterbrock} \sim 10^{-15} cm^2$$
\end{itemize}
\section*{ Lecture 8 }
Forgot something for the Einstein Analog. Recall:
$$g_1v^2\sigma_{12}(v)=g_2v^{\prime2}\sigma_{21}(v^\prime)$$
$$\hf m_ev^2=h\nu_{21}+\hf m_r(v^\prime)^2$$
For the special case of $f(v)$ being Maxwellian, then:
$${q_{12}\over q_{21}}\equiv{\mean{\sigma_{12}v}\over\mean{\sigma_{21}v}}
={g_2\over g_1}e^{-h\nu_{21}\over kT}$$
This has a Boltzmann factor, which makes you thing we're assuming LTE, but
we're not. \par
Last time, we were talking about electron-ion collisional excitation, given by:
$$\qot\equiv\mean{\sigot v}\propto\inv{v}\propto T^{-\hf}$$
We can extend this for neutral-ion collisional excitation:
$$\qot \propto T^\hf T^{-\hf} \propto T^0$$
$$\sigot\equiv{\pi\hbar^2\over m_ev^2}{\Omega(1,2)\over g}$$
where $\Omega(1,2)$ scales as $T^\hf$. Notice this means that for some
neutral-ion collisional excitation, it is {\it temperature independent}.
For neutral-neutral collisional excitation:
$$\qot=\mean{\sigot v}\propto T^\hf$$
$$\sigot\propto T^0\sim \pi(Fa_0)^2$$
This is all we'll talk about bound-bound transitions.
\subsection*{ Bound-Free Transitions (Photoionization)}
\def\sigbf{\sigma_{bf}}
We'll calculate the cross-section of a bound-free transition $\sigbf$:
$$\sigbf\sim{\lambda^2\over 8\pi}{A_{21}\over \Delta\nu}$$
It turns out that $\Delta\nu$ is about $\nu$. $\lambda\approx 912\AA$,
so scaling from Lyman-alpha:
$$\sigbf\sim{(912\AA)^3\over c\cdot8\pi}A_{21,Ly\alpha}
\left({1216\AA\over912\AA}\right)^3\sim 10^{-18}cm^2$$
It turns out that the real answer is $\sigbf\sim 6\cdot 10^{-18}cm^2$. In
general:
$$\sigbf=\sigma\eval{edge}\left({E_{photon\,in}\over E_{edge}}\right)^{-3}$$
That exponent (-3) is actually $-\frac83$ near the edge and goes to $-\frac72$
far from it. So you see $\sigbf$ spike up as the photon reaches the
ionization energy, and then decrease exponentially as energy increases.
However, you can see new spikes from ionizing electrons in inner shells.
\subsection*{ Radiative Recombination}
\def\sigfb{\sigma_{fb}}
This is the inverse process of photoionization, so $\sigfb$ is the cross-section
for an ion recapturing its electron and emitting a photon. We'll relate
$\sigfb$ to $\sigbf$. This is called the Milne Relation. In this derivation,
we'll start by assuming complete thermal equilibrium and derive a result which
will end up being independent of thermal equilibrium. Let's start calculating
the rate of radiative recombinations. Thermal equilibrium dictates that this
must equal the rate of photoionization. For radiative recombination:
$$rate\ of\ recombination
=n_+n_e\sigfb(v)v[f(v)dv]={\#\ of\ recombinations\over volume\ time}$$
We'll set this equal to the rate of photoionization. This rate is:
$$rate\ of\ photoionization
={B_\nu4\pi d\nu\over h\nu}n_0\sigbf
\overbrace{\left(1-{g_0\over g_+}{n_+\over n_0}\right)}^{{correction\ for\atop
stimulated}\atop recombination}$$
where $n_0$ is the \# density of neutrals. Note this has units of \# flux.
Note also that $\sigbf$ depends on $\nu$, and $n_+\over n_0$ is evaluated
at the relative velocity $v$ such that $h\nu=\hf m_ev^2+\chi$, where $\chi$
is the threshold ionization energy. In thermal equilibrium, we know that:
$${n_+\over n_0}={g_+\over g_0}e^{-E\over kT}$$
where $E$ is the energy difference between state 1 (proton + unbound $e^-$)
and state 2 (bound proton/electron pair). Thus $E$ is given by:
$$E=\hf m_ev^2-(-\chi)=h\nu$$
So we can make our n's and g's go away. For $f(v)$, we'll use our Maxwellian:
$$f(v)=4\pi\left({m_e\over 2\pi kT}\right)^{3\over 2}v^2e^{-m_ev^2\over 2kT}$$
Finally, Saha tells us in thermal equilibrium:
$${n_+n_e\over n_0}=\left[{2\pi m_ekT\over h^2}\right]^{3\over 2}{2g_+\over g_0}
e^{-\chi\over kT}$$
So now we're essentially done:
$$1={n_+n_ef(v)v\sigfb(v)dv\over{4\pi B_\nu\over h\nu}d\nu(1-\ehvkt)
n_0\sigbf(v)}$$
and plugging in all of our relations we get:
$$\boxed{{\sigfb(v)\over\sigbf(\nu)}=
{g_0\over g_+}\left({h\nu\over m_ecv}\right)^2}$$
\centerline{(Milne Relation)}
Notice how all of the T's vanished.
This result is independent of thermal
equilibrium. However, you still have to pay attention to your statistical
weights (g's).
\section*{ Lecture 9 }
Recall that we were deriving the Milne relation:
$${\sigfb(v)\over\sigbf(\nu)}={g_0\over g_+}\left({h\nu\over m_ecv}\right)^2$$
$(\hf m_ev^2+\chi=h\nu)$. In the following equation, Eugene has replaced
the $g_e$ of Rybicki and Lightman with the number $2$, because that is the
number of spin states of the electron. This is just to be more clear. So
the {\bf Saha} equation is:
$${n_+n_e\over n_0}=\left[{2\pi m_ekT\over h^2}\right]^{3\over2}{2g_+\over
g_0}e^{-\chi\over kT}$$
\centerline{(Saha Equation)}
Note that the number of internal degrees of freedom for the proton $g_+=2$, and
the number for neutral hydrogen:
$$g_0=\overbrace{n^2\cdot2}^{deg\ of\ freedom\ bound\ e^-}\overbrace{\cdot2}
^{proton}$$
$$g_0=4n^2$$
Beware that Shu says $g_0=2n^2$ and $g_+=2$. We are now going to write the
``Recombination Coefficient'' $\alpha$:
$$\begin{aligned}\alpha&=\sum{\int_0^\infty{\sigfb(n,v)v\,f(v)dv}}\\
&=\sum_n{\mean{\sigfb(n,v)v}}\\ \end{aligned}$$
$$\vartheta(\alpha)\simeq\vartheta\left(\sigbf({h\nu\over m_ecv})^2v\right)$$
We'll estimate that for hydrogen, $\sigbf\sim10^{-18} cm^2$, $h\nu\approx
13.6eV$, and $v\sim\sqrt{2kT\over m_e}$, where $T\sim10^4K$. Thus
$$\vartheta(\alpha)\simeq10^{-13}{cm^3\over s}\left({10^4K\over T}\right)^\hf$$
You can look this up in Osterbrock: at $T=10^4K$, the sum over all bound
states (``recombination''):
$$\alpha_A=4\e{-13}{cm^3\over s}$$
and the sum over all bound states except $n=1$ (we might be interested in
omitting the free-to-ground transition because it is likely to ionize
a nearby atom):
$$\alpha_B=2\e{-13}{cm^3\over s}$$
\subsection*{ Derivation of Saha}
Saha makes use of LTE. This equation tells us what the \# density ratio is
between states 1 and 2. We'll say that $n_{0,1}$ is the \# density of neutral
atoms with an $e^-$ in energy level 1. $n_{+,1}$ is the \# density of ionized
atoms which still have an $e^-$ in energy level 1. Saha says
collisional ionizations match the rate of collisional recombination:
$${n_+n_e\over n_0}=\left[{2\pi m_ekT\over h^2}\right]^{3\over2}{2g_+\over
g_0}e^{-\chi\over kT}$$
The Boltzmann relation says:
\def\npo{n_{+,1}}
\def\noo{n_{0,1}}
\def\gpo{g_{+,1}}
\def\goo{g_{0,1}}
$${\npo\over\noo}={\gpo\over\goo}e^{-E\over kT}$$
where $E=E_{state\ 2}-E_{state\ 1}=\hf m_ev^2-(-\chi)=\hf m_ev^2+\chi$. Now
we need to figure out our numbers of internal degrees of freedom:
$$\gpo =\gpo\eval{internal}\cdot g_e\eval{internal}\cdot
g_e\eval{translational\ motion}\cdot \gpo\eval{translational\ motion}$$